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Conference: 

IRANIAN FUEL CELL SEMINAR

Issue Info: 
  • Year: 

    2009
  • Volume: 

    3
Measures: 
  • Views: 

    118
  • Downloads: 

    70
Keywords: 
Abstract: 

IN THIS STUDY, IN ORDER TO REACH A NEW SUITABLE ELECTROLYTE FOR BETTER METHANOL ELECTRO-OXIDATION IN ACIDIC MEDIA, SOLUTION CONTAINING SYNTHETIC MODIFIER (SM) WAS USED. THESE SMS HAVE HIGH THERMAL STABILITY AND EXCELLENT IONIC CONDUCTIVITY WHICH HAS CONDUCTIVITY ABOUT 0.1 S/CM. THE METHANOL OXIDATION WAS MONITORED ON MODIFIED GC ELECTRODE WITH 10-20 %WT PT-RU/C WHICH HAS PT AND RU LOADING OF 0.051 MG/CM2 AND 0.102 MG/CM2, RESPECTIVELY. SMS IMPROVE THE METHANOL OXIDATION REACTION KINETIC BY INCREASING THE SOLUTION IONIC CONDUCTIVITY AND ALSO DECREASE THE RCT OF REACTION. THEREFORE, SM ADDED ELECTROLYTE CAN BE THE NEW PROMISING ELECTROLYTE FOR DMFCS APPLICATION.

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Conference: 

IRANIAN FUEL CELL SEMINAR

Issue Info: 
  • Year: 

    2010
  • Volume: 

    4
Measures: 
  • Views: 

    128
  • Downloads: 

    78
Abstract: 

IN RECENT YEARS, UTILIZATION OF IONIC LIQUIDS (ILS) AS ELECTROLYTE ADDITIVES IS CONSIDERED AS A NEW TOPIC IN STUDIES OF FUEL CELLS AND BATTERIES. ILS ARE MOLTEN SALTS AT AMBIENT TEMPERATURE WHICH HAVE CONSIDERABLE POTENTIAL AS HIGH TEMPERATURE ELECTROLYTE MODIFIERS DUE TO THEIR UNIQUE PROPERTIES SUCH AS NON-VOLATILITY, HIGH IONIC CONDUCTIVITY, NON-FLAMMABILITY AND HIGH THERMAL STABILITY. IN THIS WORK, EFFECT OF ILS STRUCTURE ON THE PERFORMANCE OF DMFCS ANODE HAS BEEN STUDIED BY DIFFERENT ELECTROCHEMICAL METHODS SUCH AS CYCLIC VOLTAMMETRY (CV) AND ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY (EIS). THE RESULTS SHOW THAT WITH INCREASING OF ALKYL CHAIN OF IL CATION, THE ELECTRO ACTIVITY OF CATALYST DECREASE IN METHANOL OXIDATION REACTION RELATED TO THE STRICE HINDRANCE OF IL CATION. A POSSIBLE EXPLANATION IS THAT WITH INCREASING THE NUMBER OF ALKYL CHAIN, BULK RESISTANCE INCREASED AND PROTON TRANSFER TO THE CATALYST SURFACE DECREASES AS WELL. FINALLY BY ANALYZING TEST RESULTS IT COULD BE CONCLUDED AT LOW TEMPERATURE ILS DOES NOT HAVE ANY PROMISING EFFECT ON THE CATALYST ACTIVITY AND THE ROLE OF ILS BECAME IMPORTANT AT HIGHER TEMPERATURES.

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Issue Info: 
  • Year: 

    2016
  • Volume: 

    23
Measures: 
  • Views: 

    140
  • Downloads: 

    50
Abstract: 

IN SPITE OF HIGH POWER DENSITY AND HIGH ENERGY CONVERSION EFFICIENCY OF FUEL CELLS, IN THE PATH OF WIDESPREAD COMMERCIALIZATION, THE POLYMER ELECTROLYTE MEMBRANE FUEL CELL (PEMFC) IS ENCOUNTERED WITH A NUMBER OF CHALLENGING SUCH AS HIGH PERFORMANCE AND DURABILITY [1]. ...

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Author(s): 

KAZEMPOOR P. | OMMI F.

Issue Info: 
  • Year: 

    2010
  • Volume: 

    6
  • Issue: 

    2 (20)
  • Pages: 

    11-24
Measures: 
  • Citations: 

    1
  • Views: 

    1031
  • Downloads: 

    0
Abstract: 

In this paper the PERFORMANCE of a solid oxide fuel cell (SOFC) in the ANODE-supported structure is numerically investigated. The mass, momentum, and energy equations, as well as the electrochemical and fuel reaction kinetic equations, are solved. To improve the accuracy of the results, complete electrochemical analysis, temperature dependent form of the thermodynamical and physical parameters, radiation model between the SOFC solid surfaces, and five layers of temperature are considered. The results are validated against the available experimental and numerical data and show that the cathode activation, ANODE activation, and ohmic polarizations have major effects on the cell polarization, respectively (in the order given). The molar fraction of the gas components in the fuel channel shows that the fuel internal reforming, which continues up to about 80% of the cell length, is very important in temperature distribution in the cell solid parts.

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Issue Info: 
  • Year: 

    1393
  • Volume: 

    8
Measures: 
  • Views: 

    589
  • Downloads: 

    0
Keywords: 
Abstract: 

با این که مفهوم بهره وری همیشه مورد بحث بوده، اما اغلب در آن ابهام وجود داشته و درک آن مشکل بوده است. در عمل، این همان فقدان دانشی است که نتیجه نادیده گرفته شدن نفوذ بهره وری در فرآیندهای تولیدی توسط برخی می باشد. هدف از این مقاله بحث در مورد معنی اصلی بهره وری و همچنین ارتباط آن با واژه های مشابه دیگر است که می تواند در مباحث تعاون نیز بکار برده شود. یافته ها نتیجه بررسی بهره وری بر اساس ادبیات دهه گذشته می باشد. مقاله توضیح می دهد که چگونه محققان ابهام مفهوم بهره وری را توضیح داده و یک واژه شناسی جدید برای آن ارائه می نمایند.

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Issue Info: 
  • Year: 

    2018
  • Volume: 

    37
  • Issue: 

    1
  • Pages: 

    105-112
Measures: 
  • Citations: 

    0
  • Views: 

    984
  • Downloads: 

    0
Abstract: 

Microbial Fuel Cell (MFC) is of the renewable energy in which microorganisms play the role of biocatalysts in Ox/Red reactions of a substrate like glucose. In MFC electrode is a key component. In this work, a porous nano-biocomposite electrode based on Bacterial Cellulose (BC) and polyaniline as continuous and dispersed phases respectively were synthesized by in situ chemical polymerization of 4 various concentrations of aniline. The synthesis was studied by FT-IR andFE-SEM. Then it was applied in MFC as an ANODE. PERFORMANCE of MFC was examined in presence of new ANODEs. The resistance of electrodes and produced power and current densities were measured. The maximum power of 375mW/m3 and current of 617 mA/m2 were recorded for the system for the ANODE with maximum aniline concentration.

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Issue Info: 
  • Year: 

    2018
  • Volume: 

    18
  • Issue: 

    1
  • Pages: 

    20-26
Measures: 
  • Citations: 

    0
  • Views: 

    803
  • Downloads: 

    0
Abstract: 

In this paper, the production of ANODEs of vertical titanium oxide nanotubes is analyzed and optimized by anodizing method. The parameters of the potential difference and the distance between the two electrodes in the anodize process are investigated and the effect of these parameters on morphology and ANODE structure has been investigated. The produced anodic plates, have been investigated by field-scattering electron microscope, X-ray diffraction spectrometer and radiation diffraction. The results indicate that by increasing the applied voltage from 20 to 50 Volt, the anodized nanotube diameter will increase from 50 to 155 nanometre, and after a certain voltage, the structure of the nanotubes is destroyed and nano / micro porosity is created. Also, by increasing the voltage from 20 to 50 volt, the wall thickness of the nanotubes increases from 20 to 50 nanometre. As the duration of the voltage increases, the length of the nanotubes increases; but the thickness and diameter of the nanotubes remain constant. As the gap between the two electrodes increases from 0.5 to 4.5 CM, the thickness of the walls decreases from 57 to 13 nanometre. Thus, by controlling the above mentioned parameters, the optimum state of the anodized nanotubes can be achieved to obtain a more and faster penetration of lithium ions. The results of this research are very useful in improving the PERFORMANCE of lithium ion batteries.

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Author(s): 

MOHAMMADI RAFAT

Journal: 

FUEL AND COMBUSTION

Issue Info: 
  • Year: 

    2016
  • Volume: 

    9
  • Issue: 

    1
  • Pages: 

    39-58
Measures: 
  • Citations: 

    0
  • Views: 

    954
  • Downloads: 

    0
Abstract: 

The purpose of the current study is to investigate the effects of gas flow in ANODE channel and within ANODE electrode on concentration impedance of a solid oxide fuel cell. The gas phase mass transport is modelled using transient conservation equations (momentum and species equations). Results show that gas flow and mass transport in the gas channel results in a depressed semicircle in the Nyquist plot with low relaxation frequency (less than 10Hz). In addition, gas transport in the thick porous ANODE leads to a Warburg diffusion impedance with relatively higher relaxation frequency (around 100Hz). The influences of parameters such as inlet gas velocity, electrode thickness and inlet gas compositions are also investigated and the results are discussed. From the simulation results, it is found that the EIS simulation produces a tool for both analysing experimental results of EIS and PERFORMANCE optimization of fuel cells. In addition, the developed simulation tool may allow for a reduction in the amount of costly trial and error experiments.

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Issue Info: 
  • Year: 

    2015
  • Volume: 

    11
Measures: 
  • Views: 

    141
  • Downloads: 

    49
Abstract: 

FUEL CELLS HAVE BEEN EXTENSIVELY STUDIED OVER THE LAST FIVEDECADES AND INCREASING RESOURCES HAVE BEEN USED TO BRING THEM TO A COMMERCIAL STAGE AND TO DEVELOP ALTERNATIVE FUELS TO HYDROGEN.AS PROMISING POWER SOURCES FOR SPACE AND UNDERWATER APPLICATIONS, DIRECT BOROHYDRIDE–HYDROGEN PEROXIDE FUEL CELLS (DBHPFCS), COMPRISED OF BH OXIDATION AT THE ANODE AND H O REDUCTION AT THE CATHODE, HAVE ATTRACTED INCREASING ATTENTIONS RECENTLY [1-6].IN THIS STUDY, PT/C (20 WT.%) CATHODE AND PT-NI (1: 1) /C ANODE (20 WT.%) WERE PREPARED BY THE BOROHYDRIDE REDUCTION METHOD. BRIEFLY: CARBON BLACK POWDER (VULCAN XC-72, CABOT INC.) WAS USED AS A SUPPORT FOR THE CATALYST, H2PTCL6·6H2O (MERCK, 99.99%) AND NICL2 (MERCK, 99.99%) WERE USED AS PRECURSORS. THE CARBON BLACK WAS ULTRASONICALLY DISPERSED IN A SOLUTION OF ULTRAPURE WATER AND ISOPROPYL ALCOHOL FOR 2 H. THE PRECURSORS WERE ADDED TO THE INK AND THEN MIXED THOROUGHLY FOR ANOTHER 2 H. THE PH VALUE OF THE INK WAS ADJUSTED BY A NAOH SOLUTION TO 9 AND THEN RAISED THE TEMPERATURE TO 80OC. A SOLUTION OF 0.1 MOL L-1 NABH4 WAS ADDED DROPWISE INTO THE MIXTURES, AND THE BATH WAS STIRRED FOR 3 H. THE CATALYST POWDERS WERE DRIED IN A VACUUM OVEN FOR 3 H AT 80◦C AND STORED IN A VACUUM VESSEL. TO OBTAIN A UNIFORM HIGH PURITY FILM, NAFIONÒ 117 WERE CLEANED WITH A STANDARD TREATMENT PROCEDURE WAS ADDRESED IN REF [7].PREPARED NI-PT/C AND NI/C POWDER WERE MIXED WITH 5% NAFIONSOLOUTION, WATER AND ISOPROPYL ALCOHOL SEPARATELY TO FORM CATALYST INK.THIS INK BRUSHED ON CARBON CLOTH WITH GAS DIFFUSION LAYER (GDL). THE LOADING OF GDL ON CARBON CLOTH WAS 2 MG.CM-2 AND THE LOADING OF CATHODE (NI/C) CATALYST INK WAS 0.5 MG.CM-2 BUT THE LOADING OF ANODE CATALYST INK (PT-NI/C) WAS 1 MG.CM-2. FINALLY ANODE, CATHODE AND PRE-TREATED NAFION ® 117 MEMBRANE WERE SANDWICHED TOGETHER AND HOT PRESSED. THE EFFECTIVE GEOMETRICAL AREA OF THE ANODE AND CATHODE WAS 5 CM2…

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Issue Info: 
  • Year: 

    2019
  • Volume: 

    9
  • Issue: 

    1
  • Pages: 

    217-235
Measures: 
  • Citations: 

    0
  • Views: 

    474
  • Downloads: 

    0
Abstract: 

A 3D model of computational fluid dynamics for an ANODE solid oxide fuel cell is presented. This model incorporates important transport phenomena in a fuel cell such as heat transfer, mass transfer, electrode kinetics, and potential field. The simulation results of the model were compared with the available laboratory data in the same conditions that shows good agreement with other references. In this model, the effect of different parameters such as temperature, pressure, stoichiometry and electrolyte thickness on the fuel cell PERFORMANCE was investigated. The results of this model clearly describe the distribution of species, including reactants and products, temperature distribution, distribution potential, and distribution of current density. The results showed that the temperature, pressure and stoichiometry of the ANODE have a great effect on the PERFORMANCE of the cell so that each parameter increases the PERFORMANCE of the fuel cell PERFORMANCE. On the other hand, increasing the thickness of the electrolyte can have a negative effect on the PERFORMANCE of the fuel cell.

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